Thermodynamics of the Electrolyte Solutions

An Evaluation of Four Electrolyte Models for the Prediction of Thermodynamic Properties of Aqueous Electrolyte Solutions

In this work, the performance of four electrolyte models for prediction the osmotic and activity coefficients of different aqueous salt solutions at 298 K, atmospheric pressure and in a wide range of concentrations are evaluated. In two of these models, (electrolyte Non-Random Two-Liquid e-NRTL and Mean Spherical Approximation-Non-Random Two-Liquid MSA-NRTL), association between ions of opposit...

Prediction of Surface Tension in Single and Mixed Electrolyte Solutions

Thermodynamics of Polymer Solutions

Most of the synthetic compounds are prepared and processed in the liquid state, i.e. in solution or in the molten state. Detailed knowledge on this state is therefore indispensable. In particular it is essential to know the limits of complete miscibility with a low molecular weight solvent as a function of temperature, pressure and composition. Furthermore it is often mandatory to be acquainted...

A Nonextensive Electrolyte UNIQUAC Model for Prediction of Mean Activity Coefficients of Binary Electrolyte Solutions

In this work, an electrolyte-UNIQUAC model was developed by replacement of Boltzmann weight binary interaction parameters by the nonextensive Tsallis weight. A summation of the long-range electrostatic term (Debye-Huckel equation) and a short-range interaction term were considered in the calculation of thermodynamic properties. A framework proposed by Chen and co-workers was employed for the de...

Extension of the Dense System Equation of State to Electrolyte Solutions

In this work we have applied the Dense System Equation of State (DSEOS) to electrolyte solutions. We have found that this equation of state can predict the density of electrolyte solutions very accurately. It has been tested for different electrolytes solutions at different temperatures and compositions. A hypothetical binary model has been applied to find the dependencies of parameters of ...